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Problem: Finite Size Effects

    Consider a finite size, simple cubic crystal of tex2html_wrap_inline5521 atoms, with lattice spacing a.

  (a) For tex2html_wrap_inline5525 , plot the tex2html_wrap_inline5527 -dependence of the intensity of the scattered X-rays (defined as tex2html_wrap_inline5529 , where tex2html_wrap_inline5531 is the amplitude of the scattered radiation) around the (0,0,1) point in reciprocal space. Show that there is a peak at (0,0,1) and that the peak width is finite. How is the width related to the size of the crystal tex2html_wrap_inline5533 ? How does the height of the peak depend on tex2html_wrap_inline5535 ? How does the integrated intensity behave as a function of tex2html_wrap_inline5535 ? Assume tex2html_wrap_inline5539 .

(b) What happens to the line width and the peak height if we have a collection of small crystallites, which are all oriented parallel to each other, but their positions are random?

 


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Laszlo Mihaly
Thu Oct 31 13:23:11 EST 1996


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